X-Shaped polyphilics: liquid crystal honeycombs with single-molecule walls.

نویسندگان

  • Robert Kieffer
  • Marko Prehm
  • Benjamin Glettner
  • Karsten Pelz
  • Ute Baumeister
  • Feng Liu
  • Xiangbing Zeng
  • Goran Ungar
  • Carsten Tschierske
چکیده

X-Shaped ternary five-block molecules, composed of a rigid p-terphenyl core, two terminal glycerol groups and two flexible n-alkyl or semiperfluorinated chains fixed laterally to opposite sides of the terphenyl moiety, form liquid crystalline phases built up of honeycomb-like arrays of polygonal cylinders, where the rod-like aromatic cores form cylinder walls with a thickness equal to the width of a single molecule.

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عنوان ژورنال:
  • Chemical communications

دوره 33  شماره 

صفحات  -

تاریخ انتشار 2008